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Friday, August 14, 2026

What is the relation between Electronegativity and Non-metallic character?

📚 Chapter: Classification of Elements and Periodicity in Properties

📘 Answer

Electronegativity and non-metallic character are directly related. An element having higher electronegativity generally shows a stronger non-metallic character.

Electronegativity ↑   →   Non-metallic Character ↑

Non-metals have a strong tendency to attract electrons towards themselves. Therefore, elements with high electronegativity are generally more non-metallic in nature.

🔍 Periodic Trend

Across a period:

Electronegativity generally increases from left to right, and therefore non-metallic character also increases.

Metallic Character ↓   |   Non-metallic Character ↑

Left → Right

Down a group:

Electronegativity generally decreases down a group, so non-metallic character decreases and metallic character increases.

📊 Example

In the second period:

Li → Be → B → C → N → O → F

Non-metallic character generally ↑
Electronegativity generally ↑

Fluorine has the highest electronegativity and is strongly non-metallic, whereas lithium is much more metallic and has much lower electronegativity.

✅ Final Answer

Higher electronegativity indicates a greater tendency to attract electrons and is generally associated with stronger non-metallic character.

Electronegativity ↑ → Non-metallic Character ↑

20 MCQs with Answers

1. Electronegativity and non-metallic character are generally:

A) Directly related
B) Inversely related
C) Unrelated
D) Always equal
✅ Answer

A) Directly related


2. An element with high electronegativity generally has:

A) High metallic character
B) High non-metallic character
C) Zero non-metallic character
D) No chemical activity
✅ Answer

B) High non-metallic character


3. Across a period, non-metallic character generally:

A) Decreases
B) Increases
C) Remains constant
D) Becomes zero
✅ Answer

B) Increases


4. Across a period, electronegativity generally:

A) Increases
B) Decreases
C) Remains constant
D) Has no trend
✅ Answer

A) Increases


5. Which element is strongly non-metallic?

A) Na
B) Mg
C) F
D) K
✅ Answer

C) F


6. Fluorine has a strong non-metallic character because it has:

A) Low electronegativity
B) High electronegativity
C) Large atomic size
D) Low nuclear charge
✅ Answer

B) High electronegativity


7. Down a group, non-metallic character generally:

A) Increases
B) Decreases
C) Remains constant
D) Doubles
✅ Answer

B) Decreases


8. Down a group, metallic character generally:

A) Increases
B) Decreases
C) Remains zero
D) Does not change
✅ Answer

A) Increases


9. Which property is generally associated with non-metals?

A) Low electronegativity
B) High electronegativity
C) Very large atomic size only
D) Easy loss of electrons
✅ Answer

B) High electronegativity


10. Which has greater non-metallic character?

A) Li
B) F
C) Na
D) K
✅ Answer

B) F


11. The tendency of an atom to attract shared electrons is called:

A) Ionization enthalpy
B) Electronegativity
C) Electron affinity
D) Atomic radius
✅ Answer

B) Electronegativity


12. Which trend is correct across a period?

A) Metallic character ↑, non-metallic character ↓
B) Metallic character ↓, non-metallic character ↑
C) Both decrease
D) Both remain constant
✅ Answer

B


13. High electronegativity means a stronger tendency to:

A) Lose shared electrons
B) Attract shared electrons
C) Lose protons
D) Lose neutrons
✅ Answer

B) Attract shared electrons


14. Which element is more non-metallic?

A) Na
B) Cl
C) Mg
D) Al
✅ Answer

B) Cl


15. The most electronegative element is:

A) O
B) Cl
C) F
D) N
✅ Answer

C) F


16. Non-metallic character is generally maximum toward the:

A) Bottom-left of the periodic table
B) Top-right of the periodic table
C) Centre only
D) Bottom-right only
✅ Answer

B) Top-right


17. Metallic character and electronegativity generally show:

A) Direct relationship
B) Opposite trends
C) No relationship
D) Identical values
✅ Answer

B) Opposite trends


18. Which element is expected to have greater electronegativity?

A) Na
B) Cl
C) K
D) Rb
✅ Answer

B) Cl


19. Greater electronegativity generally indicates:

A) Greater non-metallic nature
B) Greater metallic nature
C) Lower electron attraction
D) Larger atomic radius necessarily
✅ Answer

A) Greater non-metallic nature


20. Which statement is correct?

A) Electronegativity increases as non-metallic character decreases
B) High electronegativity is generally associated with high non-metallic character
C) Metals are always more electronegative than non-metals
D) Electronegativity has no periodic trend
✅ Answer

B

Q. State the relationship between electronegativity and non-metallic character.

Solution: Electronegativity and non-metallic character are generally directly related. As electronegativity increases, the tendency to attract electrons increases, so non-metallic character also increases.

Electronegativity ↑ → Non-metallic Character ↑

Q. Explain the relationship between electronegativity and non-metallic character.

Solution:

  • Non-metals have a strong tendency to attract electrons.
  • Electronegativity measures the attraction for a shared pair of electrons.
  • Therefore, higher electronegativity generally corresponds to greater non-metallic character.

Q. Explain the periodic variation of electronegativity and non-metallic character.

Solution: Across a period, effective nuclear charge increases and atomic size decreases. Therefore, electronegativity increases and non-metallic character also increases. Down a group, atomic size and shielding effect increase, causing electronegativity and non-metallic character to decrease.

Across a period: EN ↑ → Non-metallic character ↑

Down a group: EN ↓ → Non-metallic character ↓

Q. Discuss the relationship between electronegativity and non-metallic character with examples.

Solution:

Electronegativity is the tendency of an atom in a molecule to attract the shared electron pair towards itself. Non-metallic character represents the tendency of an element to accept or attract electrons.

Thus, both properties are closely related. An element with high electronegativity generally has strong non-metallic character.

For example, fluorine has the highest electronegativity and is highly non-metallic. Across a period, both electronegativity and non-metallic character generally increase.

Electronegativity ↑ → Non-metallic Character ↑

Q. Explain in detail the relationship between electronegativity and non-metallic character and discuss their periodic trends.

1. Electronegativity

Electronegativity is the tendency of an atom in a chemical bond to attract the shared pair of electrons towards itself.

2. Non-metallic Character

Non-metallic character refers to the tendency of an element to attract or gain electrons and to show properties characteristic of non-metals.

3. Relationship

Both properties depend strongly on the ability of an atom to attract electrons. Hence, they generally vary in the same direction.

Electronegativity ↑

Electron-attracting tendency ↑

Non-metallic Character ↑

4. Across a Period

From left to right, effective nuclear charge increases and atomic size decreases. Therefore, electronegativity and non-metallic character generally increase.

5. Down a Group

Down a group, atomic size and shielding effect increase. The attraction for electrons decreases. Hence electronegativity and non-metallic character generally decrease.

Across Period: EN ↑ → Non-metallic Character ↑

Down Group: EN ↓ → Non-metallic Character ↓
Key Point:
Higher electronegativity is generally associated with stronger non-metallic character.

🎯 Quick Revision

Relation: Direct relationship
Across period: Electronegativity ↑, Non-metallic character ↑
Down group: Electronegativity ↓, Non-metallic character ↓
Most electronegative: Fluorine (F)
General location of strong non-metallic character: Upper-right region