ATOMS & NUCLEI
A COMPREHENSIVE CHAPTER ANALYSIS
Physics | Class XII | CBSE / JEE / NEET
From Atomic Models to Nuclear Reactions — Everything You
Need to Master
1. INTRODUCTION TO ATOMIC STRUCTURE
Matter, in its most
fundamental form, is composed of atoms — extraordinarily minute entities that
constitute the building blocks of every substance in the known universe. The
word 'atom' originates from the ancient Greek 'atomos,' meaning indivisible. Ironically,
centuries of scientific inquiry have revealed that atoms are anything but
indivisible; they are themselves intricate systems of subatomic particles, each
governed by the laws of quantum mechanics and electrodynamics.
The atom consists of a
centrally located, positively charged nucleus — an almost incomprehensibly
dense core — surrounded by a cloud of negatively charged electrons that occupy
probabilistic regions of space known as orbitals. The nucleus itself is
composed of two types of particles: protons, which carry a positive electric
charge, and neutrons, which are electrically neutral. Together, protons and
neutrons are referred to as nucleons.
The radius of a typical
atom is on the order of 10⁻¹⁰ metres (one Angstrom), whereas the nuclear radius
is approximately 10⁻¹⁵ metres (one Femtometre or Fermi). This implies that the
nucleus occupies a fantastically small fraction of the atom's total volume —
roughly 10⁻¹⁵ of it — yet it contains nearly 99.95% of the atom's mass. If an
atom were magnified to the size of a football stadium, the nucleus would be
approximately the size of a marble at the centre.
Key Insight: An atom is
predominantly empty space. The electrons, despite defining the atom's chemistry
and size, are incredibly light compared to the nucleus.
1.1 Fundamental Subatomic Particles
|
Particle |
Symbol |
Charge |
Mass (kg) |
Location |
|
Proton |
p |
+1.6 × 10⁻¹⁹ C |
1.673 × 10⁻²⁷ kg |
Nucleus |
|
Neutron |
n |
0 (Neutral) |
1.675 × 10⁻²⁷ kg |
Nucleus |
|
Electron |
e⁻ |
−1.6 × 10⁻¹⁹ C |
9.109 × 10⁻³¹ kg |
Orbitals (shells) |
2. HISTORICAL DEVELOPMENT OF ATOMIC MODELS
The conception of the atom
has undergone a remarkable and progressive transformation over the past two
centuries. Each successive atomic model was constructed to reconcile the
discrepancies exposed by the experiments of its era, resulting in an
increasingly sophisticated and accurate description of atomic architecture.
2.1 Dalton's Atomic Theory (1803)
John Dalton, an English
chemist and physicist, proposed the first scientific atomic theory. According
to Dalton, matter consists of indivisible, indestructible particles called
atoms. He postulated that all atoms of a given element are identical in mass
and properties, that atoms of different elements differ in mass, and that
chemical reactions involve the rearrangement of atoms. While fundamentally
correct in many respects, Dalton's model had no provision for subatomic
structure and could not explain electrical phenomena.
2.2 Thomson's Plum Pudding Model (1897)
J.J. Thomson's discovery
of the electron in 1897 shattered Dalton's notion of atomic indivisibility.
Thomson proposed that the atom is a sphere of uniformly distributed positive
charge, within which negatively charged electrons are embedded like plums in a
pudding. This model, though ingenious for its time, was incapable of explaining
the nuclear scattering results that would soon emerge from Rutherford's
laboratory.
2.3 Rutherford's Nuclear Model (1911)
Ernest Rutherford's
landmark gold foil experiment, conducted with Hans Geiger and Ernest Marsden,
revolutionised the understanding of atomic structure. A beam of alpha particles
was directed at an extremely thin gold foil. While most alpha particles passed
straight through — consistent with the diffuse positive charge in Thomson's
model — a small fraction deflected at enormous angles, and some even bounced
nearly directly backwards.
Rutherford correctly
interpreted these results as evidence for a dense, positively charged nucleus
at the atom's centre. Most of the atom, he concluded, was vacant space, through
which alpha particles passed unimpeded. The rare large-angle deflections
occurred when alpha particles passed close to, or nearly collided with, the
tiny but massive nucleus. Rutherford estimated the nuclear radius to be at
least 10,000 times smaller than the atomic radius.
Figure 1: Rutherford's Gold Foil
Experiment — Revealing the Dense Atomic Nucleus
However, Rutherford's
planetary model suffered a critical flaw: according to classical
electromagnetic theory, an electron orbiting a nucleus would continuously
radiate energy, spiralling inward and causing the atom to collapse within
nanoseconds. This contradiction demanded a radical new framework — quantum
theory.
2.4 Bohr's Quantised Model (1913)
Niels Bohr resolved the
stability problem by introducing a revolutionary postulate: electrons occupy
fixed, quantised orbits (also called stationary states or energy levels) and do
not radiate energy while remaining in these orbits. Energy is emitted or
absorbed only when an electron transitions between orbits. The energy of
emitted or absorbed radiation corresponds precisely to the energy difference
between the initial and final orbits, and is quantised as a photon of energy E
= hf, where h is Planck's constant and f is the frequency.
Bohr's postulates may be
stated as follows. First, electrons revolve around the nucleus in specific
circular orbits without radiating electromagnetic energy. Second, only those
orbits are permitted for which the angular momentum of the electron is an
integral multiple of h/2π, i.e., mvr = nℏ, where n is the principal quantum
number (n = 1, 2, 3, ...). Third, when an electron transitions from a higher
energy orbit (nᵢ) to a lower energy orbit (nf), it emits a photon whose energy
equals the energy difference between the two orbits.
Figure 2: Bohr's Model — Quantised
Electron Orbits Around the Nucleus
Bohr's Key Formulae for Hydrogen Atom
Radius of nth orbit: rₙ =
n² × a₀ where a₀ = 0.529 Å
(Bohr radius)
Energy of nth level: Eₙ =
−13.6 / n² eV
Frequency of emitted photon:
hf = Eᵢ − Ef = 13.6 × (1/nf² − 1/nᵢ²) eV
The Bohr model
successfully explained the discrete spectral lines of hydrogen. The Lyman
series (transitions to n=1) lies in the ultraviolet region, the Balmer series
(transitions to n=2) falls in the visible spectrum, and the Paschen, Brackett,
and Pfund series lie in the infrared region.
|
Spectral Series |
Final Level (nf) |
Region of Spectrum |
Formula |
|
Lyman |
n = 1 |
Ultraviolet |
1/λ = R(1/1² − 1/nᵢ²) |
|
Balmer |
n = 2 |
Visible |
1/λ = R(1/2² − 1/nᵢ²) |
|
Paschen |
n = 3 |
Infrared (near) |
1/λ = R(1/3² − 1/nᵢ²) |
|
Brackett |
n = 4 |
Infrared |
1/λ = R(1/4² − 1/nᵢ²) |
|
Pfund |
n = 5 |
Far Infrared |
1/λ = R(1/5² − 1/nᵢ²) |
Here, R is the Rydberg
constant = 1.097 × 10⁷ m⁻¹. The Bohr model, while a magnificent achievement,
was limited to single-electron atoms and could not address multi-electron atoms
or the fine structure of spectral lines. It was eventually superseded by the
full quantum mechanical (wave-mechanical) model developed by Schrödinger,
Heisenberg, and Dirac.
3. THE ATOMIC NUCLEUS — STRUCTURE AND PROPERTIES
The nucleus is the heart
of the atom — an extraordinarily compact and massive entity that defines the
identity of an element and stores an immense reservoir of energy. Despite
occupying a volume roughly 10⁻¹⁵ of the total atomic volume, the nucleus
accounts for 99.95% of the atom's mass, making it one of the densest known
structures in the observable universe.
3.1 Nuclear Terminology and Notation
The composition of a
nucleus is described by two fundamental quantum numbers. The atomic number Z
denotes the number of protons within the nucleus and uniquely identifies the
chemical element. The mass number A is the total count of nucleons (protons
plus neutrons) within the nucleus. Hence, the number of neutrons N = A − Z. A
specific nuclide is represented in standard notation as ᴬ_Z X, where X is the
chemical symbol of the element.
Notation: ᴬ_Z X where
A = Mass Number, Z = Atomic
Number, N = A − Z
Isotopes are atoms of the
same element (same Z) but with different mass numbers (different A), hence
differing in neutron count. Examples include Carbon-12 (⁶¹²C) and Carbon-14
(⁶¹⁴C), or Hydrogen's three isotopes: Protium (¹H), Deuterium (²H), and Tritium
(³H). Isobars are nuclides with the same mass number A but different atomic
numbers. Isotones share the same neutron number N but differ in A and Z.
3.2 Nuclear Size and Density
Experimental evidence from
nuclear scattering experiments has established that the nuclear radius R
follows a systematic relationship with mass number A:
R = R₀ × A^(1/3)
where R₀ ≈ 1.2 × 10⁻¹⁵ m (Femtometre)
This relationship implies
that the nuclear volume V ∝ A, and therefore nuclear density is approximately
constant across all nuclides — a remarkable empirical fact. The nuclear density
is calculated to be approximately 2.3 × 10¹⁷ kg/m³, which is about 10¹⁴ times
the density of ordinary matter. A teaspoonful of nuclear matter would weigh
approximately 2 billion tonnes.
3.3 Forces Within the Nucleus
The nucleus presents a
profound puzzle from the standpoint of classical physics: how can positively
charged protons, which repel each other via the Coulomb electrostatic force,
remain bound together in such an extremely small volume? The answer lies in the
strong nuclear force — one of the four fundamental forces of nature.
•
Strong Nuclear Force: An attractive force acting
between all nucleons (proton-proton, neutron-neutron, and proton-neutron). It
is the strongest of all known forces, approximately 137 times stronger than the
electromagnetic force at nuclear distances. Crucially, it is an extremely
short-range force, effective only up to distances of about 1–3 Femtometres.
•
Electromagnetic Force (Coulomb Repulsion): Acts between
protons over unlimited range. For small nuclei, the strong nuclear force
dominates. For very large nuclei, the accumulation of Coulomb repulsion between
many protons can overcome the strong force, leading to instability.
•
Weak Nuclear Force: Responsible for beta decay
processes. It facilitates the transformation of neutrons into protons (and vice
versa) within the nucleus, playing a critical role in radioactive
transmutation.
Key Fact: The strong nuclear
force is charge-independent — it acts equally between any pair of nucleons
regardless of their charge. It is also spin-dependent and has a repulsive core
at very short distances (<0.4 fm), preventing nucleons from collapsing into
each other.
4. MASS DEFECT AND NUCLEAR BINDING ENERGY
One of the most profound
insights of modern physics is the equivalence of mass and energy, encapsulated
in Einstein's iconic equation E = mc². This principle finds one of its most
dramatic applications in the concept of nuclear binding energy.
4.1 Mass Defect (Δm)
When nucleons bind
together to form a nucleus, the mass of the resulting nucleus is measurably
less than the sum of the masses of its constituent free protons and neutrons.
This discrepancy is known as the mass defect (Δm). It is not a measurement
error but a fundamental physical reality: the missing mass has been converted
into energy, which was released when the nucleus formed and which binds the
nucleus together.
Δm = Z·mₚ + N·mₙ − M_nucleus
Where mₚ = mass of a
proton = 1.00728 u, mₙ = mass of a neutron = 1.00866 u, M_nucleus is the actual
measured mass of the nucleus, and u = unified atomic mass unit = 1.66054 ×
10⁻²⁷ kg.
4.2 Nuclear Binding Energy (Eₔ)
The binding energy is the
energy equivalent of the mass defect, calculated using Einstein's mass-energy
relation. It represents the minimum energy that must be supplied to completely
disassemble the nucleus into its constituent free nucleons.
Eₔ = Δm · c² (in Joules)
Eₔ (in MeV) = Δm (in u) × 931.5 MeV/u
The binding energy per
nucleon, Eₔ/A, is a crucial measure of nuclear stability. It represents how
tightly each nucleon is bound within the nucleus. A higher binding energy per
nucleon signifies a more stable nucleus.
Figure 3: Binding Energy per Nucleon vs.
Mass Number — The Stability Curve of the Nucleus
As illustrated in the
graph, the binding energy per nucleon rises steeply for light nuclei, reaches a
broad maximum of approximately 8.79 MeV per nucleon at Iron-56 (⁵⁶Fe), and then
gradually decreases for heavier nuclei. This curve has profound consequences
for nuclear energy:
•
Fusion (light elements joining): Moving up the curve
from left toward the iron peak releases energy, because the products are more
tightly bound than the reactants.
•
Fission (heavy elements splitting): Moving down the
curve from right toward the iron peak also releases energy, for the same reason
— the fission products are more stable (higher Eₔ/A) than the parent nucleus.
•
Iron is the most stable element in the universe. It is
the endpoint of stellar nuclear synthesis through fusion, and further fusion or
fission of iron actually requires energy input rather than releasing it.
Historical Note: The
development of nuclear weapons and power plants in the 20th century was made
possible by the profound insight that tiny mass defects — millionths of a
kilogram — translate, via E=mc², into enormous energy releases of millions of
electron-volts per reaction.
5. RADIOACTIVITY — SPONTANEOUS NUCLEAR TRANSFORMATION
Radioactivity is the
spontaneous emission of radiation from an unstable nucleus as it seeks a more
stable configuration. Discovered by Henri Becquerel in 1896 and extensively
studied by Marie and Pierre Curie, radioactivity revealed that certain atomic
nuclei are inherently unstable and undergo spontaneous transformation, emitting
energetic particles or electromagnetic radiation in the process.
The phenomenon is entirely
spontaneous and cannot be accelerated, retarded, or controlled by any chemical
or physical means — temperature, pressure, magnetic or electric fields have
absolutely no effect on the rate of radioactive decay. This underscores that
radioactivity is a purely nuclear phenomenon, governed by quantum mechanical
probability.
5.1 Types of Radioactive Decay
Figure 4: The Three Types of Radioactive
Decay and Their Relative Penetrating Powers
Alpha (α) Decay
In alpha decay, the
nucleus emits an alpha particle — a tightly bound cluster of two protons and
two neutrons (equivalent to a helium-4 nucleus, ⁴₂He). This occurs
predominantly in heavy nuclei (A > 200) where the ratio of protons to
neutrons makes the nucleus unstable against proton-proton Coulomb repulsion.
ᴬ_Z X → ᴬ⁻⁴_(Z-2) Y
+ ⁴₂He +
Energy
Alpha particles possess
high kinetic energy (typically 4–9 MeV) but have very low penetrating power due
to their large charge (+2e) and relatively large mass. They are stopped by a
few centimetres of air or a single sheet of paper. Despite low penetration,
they are extremely ionising and pose serious radiological hazard if
alpha-emitting materials are ingested or inhaled.
Beta (β) Decay
Beta decay occurs in two
varieties. In beta-minus (β⁻) decay, a neutron within the nucleus transforms
into a proton, simultaneously emitting an electron (β⁻ particle) and an
electron antineutrino (ν̄ₑ). The atomic number increases by one while the mass
number remains unchanged.
ᴬ_Z X → ᴬ_(Z+1) Y
+ e⁻ + ν̄ₑ
In beta-plus (β⁺) decay, a
proton transforms into a neutron, emitting a positron (the antimatter counterpart
of the electron) and an electron neutrino (νₑ). The atomic number decreases by
one.
ᴬ_Z X → ᴬ_(Z-1) Y
+ e⁺ + νₑ
The neutrinos are
essentially massless, electrically neutral particles that interact extremely
weakly with matter and pass through virtually everything. The continuous energy
spectrum of beta particles (rather than discrete energies) was a major puzzle until
Pauli proposed the existence of the neutrino in 1930 to conserve energy and
momentum.
Gamma (γ) Radiation
Gamma radiation consists
of high-energy photons emitted when a nucleus transitions from an excited
energy state to a lower energy state. Gamma emission often accompanies alpha or
beta decay, as the daughter nucleus may initially be left in an excited state.
Unlike alpha and beta decay, gamma emission does not change the atomic number
or mass number of the nucleus.
ᴬ_Z X* → ᴬ_Z X
+ γ (photon)
Gamma rays have extremely
high penetrating power — they require several centimetres of lead or metres of
concrete to be effectively attenuated — but are far less ionising per unit path
length than alpha or beta particles.
|
Property |
Alpha (α) |
Beta (β) |
Gamma (γ) |
|
Nature |
He-4 nucleus (²p + ²n) |
Electron or Positron |
High-energy photon |
|
Charge |
+2e |
±e |
0 |
|
Mass |
~6.64 × 10⁻²⁷ kg |
~9.1 × 10⁻³¹ kg |
0 (massless) |
|
Speed |
~5–7% of c |
Up to ~99% of c |
c (speed of light) |
|
Ionising Power |
Highest (~10,000×) |
Moderate (~100×) |
Lowest (1×) |
|
Penetration |
~4 cm air / paper |
~3 mm aluminium |
Several cm lead |
5.2 The Law of Radioactive Decay
Radioactive decay is a
statistical, probabilistic process governed by quantum mechanics. Each nucleus
of an unstable species has a fixed probability of decaying per unit time,
independent of its history, the presence of other nuclei, or any external conditions.
This leads to exponential decay behaviour.
If N₀ is the initial
number of radioactive nuclei at time t = 0, then the number of undecayed nuclei
at time t is given by the fundamental decay law:
N(t) = N₀ · e^(−λt)
Here, λ is the decay
constant, which represents the probability of decay per nucleus per unit time.
It is characteristic of each particular radioactive isotope.
Figure 5: Exponential Radioactive Decay
— The Half-Life Concept Illustrated
Half-Life (T₁/₂)
The half-life T₁/₂ is the
time required for exactly half the original number of radioactive nuclei to
decay. It is the most commonly cited measure of a radioisotope's rate of decay
and is related to the decay constant by:
T₁/₂ = ln(2) / λ ≈ 0.693 / λ
After each successive
half-life, half of the remaining nuclei decay. Thus, after n half-lives, the
fraction remaining is (1/2)ⁿ. Half-lives span an extraordinary range — from
fractions of a microsecond for the most unstable nuclei to billions of years
for nearly stable ones. For example, Carbon-14 has a half-life of 5,730 years
(used in radiocarbon dating), while Uranium-238 has a half-life of 4.47 × 10⁹
years.
Activity (A)
The activity of a
radioactive sample is the number of disintegrations per second. It is
proportional to the number of undecayed nuclei:
A = λN = λN₀ · e^(−λt) = A₀ · e^(−λt)
The SI unit of activity is
the Becquerel (Bq), defined as one disintegration per second. The older unit is
the Curie (Ci), where 1 Ci = 3.7 × 10¹⁰ Bq.
6. NUCLEAR REACTIONS — FISSION AND FUSION
Nuclear reactions involve
transformations of nuclei, accompanied by the release or absorption of energy.
The two most energetically significant nuclear reactions are fission — the
splitting of heavy nuclei — and fusion — the joining of light nuclei. Both
derive their enormous energy output from the mass-energy equivalence principle
and from the shape of the binding energy per nucleon curve.
6.1 Nuclear Fission
Nuclear fission is the
process by which a heavy nucleus (typically Uranium-235 or Plutonium-239)
absorbs a slow (thermal) neutron and splits into two intermediate-mass daughter
nuclei (fission fragments), releasing two or three additional neutrons and a
substantial quantity of energy — approximately 200 MeV per fission event. This
energy is primarily in the kinetic energy of the fission fragments and
neutrons, which is ultimately converted to heat.
²³⁵₉₂U + ¹₀n
→ [²³⁶₉₂U]* →
⁹²₃₆Kr + ¹⁴¹₅₆Ba
+ 3 ¹₀n +
Energy (~200 MeV)
Figure 6: Nuclear Fission Chain Reaction
— The Mechanism Behind Nuclear Reactors and Weapons
The critical feature of
nuclear fission is the chain reaction: the neutrons released in each fission
event can induce further fission in neighbouring nuclei, potentially leading to
an exponentially growing cascade of fissions. If the mass of fissile material
exceeds the critical mass — the minimum mass required to sustain a
self-perpetuating chain reaction — an uncontrolled chain reaction produces a
nuclear explosion. In a nuclear reactor, the chain reaction is controlled by
moderators (to slow neutrons) and control rods (to absorb excess neutrons),
maintaining a steady, sustainable reaction rate.
Applications: Nuclear fission
powers approximately 10% of the world's electricity through nuclear power
plants. It also represents the destructive force of fission nuclear weapons
(atomic bombs), first detonated in 1945.
6.2 Nuclear Fusion
Nuclear fusion is the
process by which two light nuclei collide and merge to form a heavier nucleus,
releasing energy. Fusion powers every star in the universe, including our Sun.
The primary fusion reaction in the Sun is the proton-proton chain, which
ultimately fuses four hydrogen nuclei (protons) into one helium-4 nucleus,
releasing about 26.7 MeV of energy per cycle.
²₁H + ³₁H
→ ⁴₂He + ¹₀n + 17.6
MeV (Deuterium-Tritium fusion)
Fusion reactions require
the reactant nuclei to approach each other to within the range of the strong
nuclear force (~1 fm), overcoming the enormous electrostatic repulsion between
their positive charges. This requires temperatures of the order of 10⁷ to 10⁸
Kelvin, at which matter exists as a plasma (fully ionised gas). These
conditions exist in the cores of stars and in thermonuclear weapons (hydrogen
bombs).
Controlled nuclear fusion
for peaceful power generation is the subject of intensive global research. If
achieved, it promises virtually limitless clean energy — the fuels (deuterium
and lithium) are abundantly available, and the primary by-product (helium) is
non-radioactive. Major experimental facilities like ITER (International
Thermonuclear Experimental Reactor) in France are working toward achieving
sustained fusion reactions.
|
Feature |
Nuclear Fission |
Nuclear Fusion |
|
Process |
Heavy nucleus splits |
Light nuclei merge |
|
Energy per reaction |
~200 MeV (U-235) |
~17.6 MeV (D-T) |
|
Energy per kg of fuel |
~8.2 × 10¹³ J |
~3.4 × 10¹⁴ J (>4×
fission) |
|
Fuel |
U-235, Pu-239 (rare) |
D & T from
hydrogen/lithium (abundant) |
|
Radioactive waste |
Long-lived fission
fragments |
Minimal (mainly He) |
|
Condition required |
Critical mass, slow
neutrons |
~10⁸ K plasma (very
difficult) |
|
Current status |
Widely used in power plants |
Experimental (ITER, NIF) |
7. NUCLEAR ENERGY AND ITS APPLICATIONS
The extraction of nuclear
energy — whether from fission or fusion — represents perhaps the most
transformative technological application of modern physics. The energy yield
from nuclear reactions dwarfs that of any chemical process by a factor of
millions. Just one kilogram of Uranium-235 undergoing complete fission releases
energy equivalent to burning approximately 3,000 tonnes of coal.
7.1 Nuclear Reactor
A nuclear reactor is a
device in which a controlled, self-sustaining nuclear fission chain reaction is
maintained to produce heat, which is then used to generate electricity via
steam turbines. The essential components include: the fuel (enriched uranium or
plutonium), the moderator (heavy water, graphite, or light water — used to slow
neutrons to thermal speeds optimal for fission), control rods (boron or cadmium
rods that absorb neutrons to regulate the reaction rate), the coolant (water,
heavy water, or liquid sodium — removes heat from the reactor core), and the
reactor vessel and biological shielding (to contain radiation).
7.2 Applications of Radioactivity
•
Radiocarbon Dating (¹⁴C): Carbon-14 is produced in the
upper atmosphere and absorbed by living organisms. When an organism dies, ¹⁴C
is no longer replenished and decays with a half-life of 5,730 years. By
measuring the ratio of ¹⁴C to ¹²C, archaeologists can date organic materials up
to ~50,000 years old with remarkable precision.
•
Medical Diagnosis (Nuclear Medicine): Radioisotopes
such as Technetium-99m are used in PET (Positron Emission Tomography) and SPECT
scans to image internal organs, detect tumours, and assess blood flow without
invasive procedures.
•
Radiation Therapy: High-energy gamma rays from
Cobalt-60 or focused beams of particles are used to destroy cancerous tumours
with precision, minimising damage to surrounding healthy tissue.
•
Industrial Applications: Gamma radiography is used to
detect flaws in metal castings, welds, and pipelines (non-destructive testing).
Thickness gauges use beta particle absorption to control manufacturing tolerances.
•
Smoke Detectors: Americium-241 ionises air inside the
detector. Smoke particles disrupt the ion current, triggering the alarm — a
ubiquitous everyday application of radioactivity.
8. IMPORTANT FORMULAE AND QUICK REFERENCE
|
Quantity / Concept |
Formula |
Units / Remarks |
|
Bohr radius (n=1) |
a₀ = 0.529 Å |
Radius of H ground state
orbit |
|
Radius of nth orbit |
rₙ = n² a₀ |
H atom only |
|
Energy of nth level (H) |
Eₙ = −13.6/n² eV |
Ground state: n=1, E₁=−13.6
eV |
|
Nuclear radius |
R = R₀ A^(1/3) |
R₀ = 1.2 fm = 1.2×10⁻¹⁵ m |
|
Mass defect |
Δm = Zmₚ + Nmₙ − M |
In unified atomic mass
units (u) |
|
Binding energy |
Eᵦ = Δm × 931.5 MeV |
Per nucleus; 1 u = 931.5
MeV/c² |
|
Radioactive decay law |
N(t) = N₀ e^(−λt) |
λ = decay constant (s⁻¹) |
|
Half-life |
T½ = 0.693/λ |
Time for half the nuclei to
decay |
|
Activity |
A = λN |
Unit: Becquerel (Bq) = 1
decay/s |
|
Mass-energy equivalence |
E = mc² |
c = 3×10⁸ m/s |
|
Energy-momentum relation |
E² = (pc)² + (m₀c²)² |
For relativistic particles |
|
Rydberg formula |
1/λ = R(1/nf² − 1/nᵢ²) |
R = 1.097×10⁷ m⁻¹ |
9. SOLVED EXAMPLES
Example 1: Calculate the binding energy of ⁴₂He (Alpha Particle)
Given: Mass of ⁴₂He
nucleus = 4.00150 u, mₚ = 1.00728 u, mₙ = 1.00866 u
Δm = 2(1.00728) + 2(1.00866) − 4.00150 = 2.01456 + 2.01732 −
4.00150 = 0.03038 u
Eᵦ = 0.03038 × 931.5 = 28.30 MeV
Binding energy per nucleon = 28.30 / 4 = 7.07 MeV/nucleon
Example 2: Half-Life Calculation
A radioactive sample has
an initial activity of 4000 Bq. After 30 minutes, the activity is 500 Bq. Find
the half-life.
A/A₀ = (1/2)^n → 500/4000 = (1/2)^n → 1/8
= (1/2)³ → n = 3
Therefore, 3 half-lives = 30 min
→ T½ = 10 minutes
Example 3: Energy Released in Fission
If 1 gram of U-235
undergoes complete fission, each releasing 200 MeV, calculate the total energy
released.
Number of atoms = (1/235) × 6.022×10²³ = 2.56×10²¹ atoms
Total energy = 2.56×10²¹ × 200 MeV = 5.12×10²³ MeV = 8.2×10¹⁰ J
≈ 82 GJ
10. CHAPTER SUMMARY AND KEY TAKEAWAYS
The chapter on Atoms and
Nuclei represents one of the most intellectually profound journeys in all of
physics — from the philosophical concept of the indivisible atom to the
practical harnessing of nuclear energy that powers cities and enables
life-saving medical technologies.
•
Atomic models evolved from Dalton (solid indivisible
spheres) through Thomson (plum pudding), Rutherford (nuclear planetary model),
and Bohr (quantised orbits) to the modern quantum mechanical orbital model.
Each model corrected specific flaws of its predecessor.
•
The nucleus is an extraordinarily dense, positively
charged core whose radius scales as R = R₀A^(1/3). It is held together by the
short-range, charge-independent strong nuclear force, which overcomes Coulomb
repulsion.
•
Mass defect (Δm) and binding energy (Eᵦ = Δmc²) explain
the remarkable stability of nuclei. The binding energy per nucleon peaks at
Iron-56, which dictates that both fission of heavy nuclei and fusion of light
nuclei release energy.
•
Radioactive decay — alpha, beta, and gamma — are
spontaneous, quantum mechanical processes following the exponential decay law N
= N₀e^(−λt). The half-life is an intrinsic property of each nuclide.
•
Nuclear fission (splitting of U-235/Pu-239) releases
~200 MeV per event and sustains chain reactions used in nuclear reactors and
weapons. Nuclear fusion (merging of H isotopes) releases even more energy per
unit mass and powers the Sun.
•
Applications of nuclear physics permeate modern life:
power generation, medical imaging and cancer therapy, archaeological dating,
industrial non-destructive testing, and smoke detection.
"The energy available from nuclear reactions dwarfs
that of all chemical reactions combined.
It is the energy that forges stars and, in our hands,
transforms civilisation."
— Class XII Physics
| Atoms & Nuclei Chapter Analysis